Fester, Victor and Nicholson, Brian and Main, Lyndsay (2007) (6-Acetoxy-2-acetylphenyl-κ²C¹,O¹)tetracarbonylmanganese(I). Acta Crystallographica Section E: Structure Reports Online, 63 (11). ISSN 1600-5368
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Official URL: http://dx.doi.org/10.1107/S1600536807047605
Abstract
The title compound, [Mn(C10H9O3)(CO)4], is formed by orthomanganation of 3'-acetoxyacetophenone at the sterically crowded ortho site. The atoms of the benzene and the cyclometallated rings are coplanar to within <0.018 Å, and there are no significant intramolecular interactions between the Mn(CO)4 group and the adjacent acetoxy group.
| Item Type: | Article |
|---|---|
| Keywords: | chemistry, organometallic chemistry, manganese |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Schools > School of Science and Primary Industries |
| ID Code: | 459 |
| Deposited By: | |
| Deposited On: | 27 Nov 2009 03:50 |
| Last Modified: | 16 Sep 2010 23:37 |
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