(6-Acetoxy-2-acetylphenyl-κ²C¹,O¹)tetracarbonylmanganese(I)

Fester, Victor and Nicholson, Brian and Main, Lyndsay (2007) (6-Acetoxy-2-acetylphenyl-κ²C¹,O¹)tetracarbonylmanganese(I). Acta Crystallographica Section E: Structure Reports Online, 63 (11). ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536807047605

Abstract or Summary

The title compound, [Mn(C10H9O3)(CO)4], is formed by orthomanganation of 3'-acetoxyacetophenone at the sterically crowded ortho site. The atoms of the benzene and the cyclometallated rings are coplanar to within <0.018 Å, and there are no significant intramolecular interactions between the Mn(CO)4 group and the adjacent acetoxy group.

Item Type:Journal article
Keywords that describe the item:chemistry, organometallic chemistry, manganese
Subjects:Q Science > QD Chemistry
Divisions:Schools > Centre for Science and Primary Industries
ID Code:459
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Deposited On:27 Nov 2009 03:50
Last Modified:16 Sep 2010 23:37

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