A manganese carbonyl complex derived from the P,N-bonding ligand (2-aminophenyl)diphenylphosphine

Fester, Victor and Houghton, Paul and Main, Lyndsay and Nicholson, Brian (2007) A manganese carbonyl complex derived from the P,N-bonding ligand (2-aminophenyl)diphenylphosphine. Polyhedron, 26 (2). pp. 430-433. ISSN 0277-5387

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Official URL: http://dx.doi.org/10.1016/j.poly.2006.06.034

Abstract or Summary

Thermal reaction of [H3Mn3(CO)12] with Ph2PC6H4NH2-2 gives good yields of [Mn2(CO)6(PPh2C6H4NH)2], an X-ray single crystal structure determination of which reveals a P,N-chelating ligand with each of the NH groups, formed by deprotonation of the amine groups, bridging the two metal atoms.

Item Type:Journal article
Keywords that describe the item:mamganese carbonyl, hemilabile, x-ray crystal structure, 2-aminophenyldiphenylphosphine
Subjects:Q Science > QD Chemistry
Divisions:Schools > Centre for Science and Primary Industries
ID Code:460
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Deposited On:30 Nov 2009 00:34
Last Modified:09 Apr 2010 02:35

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